Sounds like you have a good shop. They will tell you what needs replacing first because if they know what they are doing, they can't even align it properly with worn parts.
As for eyeballing the toe, the human eyeball is actually pretty precise. Here is an interesting bit of trivia about the Trailblazer. The front fender lip just above the tire is almost exactly parallel to the tire line, and you can use it to compare side to side. Next time you park it, park it with the wheel dead straight then eyeball the line of the wheel in comparison to the line of the fender lip when viewed from directly above. Actually, the fender line is very slightly narrower at the front than the back, but the front tires should have a bit (about 1/2" to 3/4") of toe in anyway. If you get really ambitious, lay or bungee a straight piece of wood across the wheel and tire, parallel to the ground as close to the center as possible. Then eyeball that stick from above. If there is a difference side by side, you have found your problem.
Just for fun and future info for others reading this thread, this is actually the way I get my toe roughly adjusted in my driveway when I replace outer tie rod ends. I use L-shaped or U-shaped aluminum channel, about 3 feet long, bungeed to my wheel. Once I get both tires exactly the same and both absolutely dead straight in comparison to the line of the fender lip, I use two tape measures stretched across from tire to tire, one on front and one behind. (This is the part that takes the time to be precise, and one will dive underneath the truck about 40 to 50 times before it is perfect.) If you work carefully, you can get the toe as precise as any computer alignment machine. Assuming the fender line is straight, with no damage, I get both sides exactly the same and exactly parallel to the fender line, then start adjusting toe in so the back measurement is 3/4" greater. The slow part is that every adjustment has to be halved from side to side to keep the wheels exactly the same and exactly dead straight. (Be sure the steering wheel does not move from dead straight.)
Another interesting bit of trivia. This method of eyeballing the toe and then measuring with two tape measures is what we used to do in the 1980s when we adjusted the toe on our endurance road race car. We used a bit of toe in for long tracks where we needed stability on a straight line, and a bit of toe out for short tracks to help it nip into a corner quicker. (Toe out makes it more challenging to drive in a straight line though.)
So, just for fun, go eyeball your wheel line in comparison to the fender lip when viewed from above, and you will see what I mean. If the wheels seem to be pointed outward slightly, even by a little bit, your toe is out. If one is pointed dead straight and the other is pointed outward slightly - which is what I suspect - then you have found your problem.