I never use heat on brake parts. Just boils the system and causes the internal rubber seals to burn up.
Spray with PB Blaster, tap with hammer (not hard, just to make the parts vibrate), then wait 15 minutes. Tap again, then USING THE CORRECT TOOL, slightly tighten the bleeder first, then it will generally pop loose.
If not, just change out the entire cylinder (drum brakes) or caliper (disk brakes) for if the parts are corroded to that level they are due for replacement anyway. Might also want to change the hoses and check the lines at that time as well.
Generally, if a part is THAT corroded then it is ready for the scrap heap and we must bear in mind that brake fluid also corrodes from the inside as it collects humidity from the atmosphere and will actually rust inside the system at about the same speed as it does the outside of the system. That is the reason that brake fluid is changed in the first place, for it really doesn't go bad, but it DOES collect moisture and that moisture is the death of any brake system!