EDIT:
Check to see if your Plastic Intake Manifold Bolts-Fasteners are loose enough to allow for vacuum leaks around the intake ports... Remember when you were either removing, installing or cleaning the Throttle Body? It is entirely possible that the Plastic Intake Manifold was also being moved around a bit and that would allow the sealing "O" Rings the chance to be moved enough and cause the ports to break their rubber gasket seals and pull in ambient air to lean out the the air-fuel ratios and cause misfires as a result. You do not have to remove the IM...just go around and tighten up the fasteners...tight...but NOT TOO tight...and see what happens. Look up "How To R&R The Trailblazer 4.2l Intake Manifold" to find images...or excerpts from the manual.
Do you a desire to learn how to do any of these repairs...or can you engage the assistance of someone in your circle of friends who might be both mechanically knowledge-capable...and keen to help you with looking into these issues? We can hold your hand to figure out what is wrong to some extent...but eventually...it might be necessary to turn a wrench or two and get after things first hand.
Doing most of the "fixes' on the vehicle will not be over-whelming and if you visit Youtube and look a GMT Nation Member named "MAY03LT" AKA
@MAY03LT and view any of his many target specific repairs...you could develop your mechanical aptitude very confidently and quickly if your desire to save money and learn are present in equal measure.ir
Here is an interesting video on how to diagnose and repair your Secondary Air PO014 code issue...even if you do not understand a word of what he is talking about...he will TELL you that the pump his is examining will need to be changed.: